Biomass chemical looping gasification (BCLG) is a promising key expertise for producing carbon impartial liquid biofuels. Nevertheless, numerous ash-related points, similar to mattress agglomeration, fouling and slagging, or high-temperature corrosion could trigger important financial and ecologic challenges for dependable implementation of BCLG. Biomass pre-treatment strategies, similar to torrefaction, (water-)leaching and mixture of each approaches could considerably enhance ash-related traits and due to this fact present a promising method for enabling using herbaceous residues. This examine offers with important lab-scale investigations beneath well-defined, gasification-like circumstances at 950 °C, joint with thermodynamic equilibrium calculations. Basic data on the affect of pre-treatment strategies on the discharge and destiny of unstable inorganics in addition to on the ash melting habits of the residual ashes was gained. Molecular Beam Mass Spectrometry (MBMS) was utilized for in situ on-line sizzling gasoline evaluation of (non-)condensable gasoline species throughout gasification of pre-treated feedstocks. Each ash composition and habits had been characterised notably by X-ray powder diffraction technique and sizzling stage microscopy (HSM). The outcomes obtained by chemical characterization had been taken into consideration for thermodynamic modelling. Based mostly on the outcomes, conclusions had been drawn on how totally different pre-treatment applied sciences can assist to enhance and remedy ash-related points throughout thermochemical conversions. It has been demonstrated that (mixed) pre-treatment strategies can counteract the above-mentioned issues and have a noticeable impact on the principal inorganic constituents (e.g. Okay, Ca, Si) originating from the ash by shifting their proportions.